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Absorption Spectroscopy and Dielectric Properties of Zinc Borate Glasses Modified by BaTiO3 Ceramics
F. Khrongchaiyaphum(1),(2), N. Triamnak(3), R. Yimnirun(4), N. Wantana(1),(2), W. Chaiphaksa(1),(2), J. Kaewkhao(1),(2), and T. Sareein(5*)

1) Physics Program, Faculty of Science and Technology, Nakhon Pathom Rajabhat University, Nakhon Pathom 73000, THAILAND
2) Center of Excellence in Glass Technology and Materials Science (CEGM), Nakhon Pathom Rajabhat University, Nakhon Pathom 73000, THAILAND
3) Department of Materials Science and Engineering,
Faculty of Engineering and Industrial Technology, Silpakorn University,
Nakhon Pathom, 73000, THAILAND
4) School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong, 21210, THAILAND
5) Division of Industrial Materials Science, Faculty of Science and Technology, Rajamangala University of Technology Phra Nakhon, Bangkok 10800, THAILAND
*thanapong.s[at]rmutp.ac.th


Abstract

The effect of BaTiO3 concentration on borate glass were investigated, with various BaTiO3 content and different ZnO-B2O3 solution as the sintering aids by melting quenching technique. X-ray diffraction technique confirmed the formation of powder mixtures. The density of glass is increased with increasing the amount of BaTiO3 concentration, while molar volume and refractive index were slightly altered. Absorption spectra were measured, and optical band gap were determined. Absorption bands were not discovered in the visible light spectrum. The dielectric behavior which is also observed of BaTiO3-ZnO-B2O3 system were systematically investigated. The dielectric of BaTiO3 concentration on borate glass with good permittivity and low dielectric loss were obtained at high concentrations the amount of BaTiO3. Furthermore, radiation shielding properties were calculated and found better when increasing of BaTiO3. This developed glass could be used for transparency radiation shielding materials.

Keywords: Transmission spectrum- relaxation- BaTiO3- lead-free

Topic: Theory and Design

Plain Format | Corresponding Author (Thanapong Sareein)

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